133744-99-7Relevant academic research and scientific papers
Phosphasilene synthesis and reactivity: an improved route to 1-(2,4,6-tri-tert-butylphenyl)-2-tert-butyl-2-(2,4,6-tri-isopropylphenyl)phosphasilene
Winkel, Yvar van den,Bastiaans, Harold M. M.,Bickelhaupt, Friedrich
, p. 183 - 194 (2007/10/02)
A new route was developed for the synthesis of a specific phosphasilene, 1-(2,4,6-tri-tert-butylphenyl)-2-tert-butyl-2-(2,4,6-tri-isopropylphenyl)phosphasilene (1e).Several novel phosphasilenes (1) with various substituents on phosphorus have been synthesized.The influence of the substituents on the phosphorus and silicon chemical shifts and the stability of the phosphasilenes is analyzed.The chemical reactivity of 1e has been investigated.
RECENT DEVELOPMENTS IN PHOSPHASILENE CHEMISTRY
Winkel, Yvar van den,Bastiaans, Harold M. M.,Bickelhaupt, Friedrich
, p. 333 - 336 (2007/10/02)
An alternative route to phosphasilenes is discussed and several new phosphasilenes, with variation of the substituents on phosphorus, have been synthesized.The influence of the substituents on the phosphorous and silicon chemical shifts, as well as on the stability of the phosphasilenes is analyzed.The chemical reactivity of one of the phosphasilenes was explored.
