13375-26-3

Basic information

• Product Name: 1-allyl-1-methylcyclohexanone
• Synonyms: 1-allyl-1-methylcyclohexanone
• CAS NO: 13375-26-3
• Molecular Weight: 138.253
• Mol File: 13375-26-3.mol
• Article Data: 4

Chemical Properties

• CAS DataBase Reference: 1-allyl-1-methylcyclohexanone(CAS DataBase Reference)
• NIST Chemistry Reference: 1-allyl-1-methylcyclohexanone(13375-26-3)
• EPA Substance Registry System: 1-allyl-1-methylcyclohexanone(13375-26-3)

Safety Data

• Hazardous Substances Data: 13375-26-3(Hazardous Substances Data)

Upstream product

• 931-78-2 1-chloro-1-methylcyclohexane 
• 1730-25-2 allylmagnesium bromide 
• 590-67-0 1-Methylcyclohexanol 
• 762-72-1 allyl-trimethyl-silane 
• 54927-71-8 trimethyl((1-methylcyclohexyl)oxy)silane 
• 931-77-1 1-bromo-1-methylcyclohexane 
• 24850-33-7 allyltributylstanane 

Downstream Products

• 4258-93-9 1-methyl-1-propylcyclohexane 

Relevant articles and documents

Carbon-Carbon Bond Formation via the Reaction of Trialkylallylstannanes with Organic Halides

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InCl3-catalyzed cross-coupling of alkyl trimethylsilyl ethers and allylsilanes via an in situ derived combined lewis acid of InCl3 and Me3SiI

(Chemical Equation Presented) Direct Csp3-Csp3 coupling of various aliphatic trimethylsilyl ethers and allylsilanes is effectively catalyzed by InCl3 and I2. The transformation is thought to involve an in situ-derived combined Lewis acid of InCl3 and Me3SiI. The reaction can be used for the construction of quaternary-quaternary and quaternary-tertiary carbon-carbon bonds. This system enabled a highly chemoselective coupling to be conducted with a trimethylsilyl ether including an aryl halide moiety. Furthermore, couplings were possible using an alkynyltri-methylsilane and a trimethylsilyl ketene acetal.