1337568-05-4

Basic information

• Product Name: [(MeC(N(2,6-(i-Pr)2-C6H3))CHC(Me)(NCH2CH2NMe2))Y(NH(2,6-(i-Pr)2-C6H3))(η2-(N,N')-(i-Pr)NCHN(i-Pr))]
• CAS NO: 1337568-05-4
• Molecular Weight: 720.918
• Mol File: 1337568-05-4.mol

Chemical Properties

• CAS DataBase Reference: [(MeC(N(2,6-(i-Pr)2-C6H3))CHC(Me)(NCH2CH2NMe2))Y(NH(2,6-(i-Pr)2-C6H3))(η2-(N,N')-(i-Pr)NCHN(i-Pr))](CAS DataBase Reference)
• NIST Chemistry Reference: [(MeC(N(2,6-(i-Pr)2-C6H3))CHC(Me)(NCH2CH2NMe2))Y(NH(2,6-(i-Pr)2-C6H3))(η2-(N,N')-(i-Pr)NCHN(i-Pr))](1337568-05-4)
• EPA Substance Registry System: [(MeC(N(2,6-(i-Pr)2-C6H3))CHC(Me)(NCH2CH2NMe2))Y(NH(2,6-(i-Pr)2-C6H3))(η2-(N,N')-(i-Pr)NCHN(i-Pr))](1337568-05-4)

Safety Data

• Hazardous Substances Data: 1337568-05-4(Hazardous Substances Data)

Upstream product

• 693-13-0 diisopropyl-carbodiimide 

Relevant articles and documents

Yttrium anilido hydride: Synthesis, structure, and reactivity

The synthesis, structure, and reactivity of the yttrium anilido hydride [LY(NH(DIPP))(μ-H)]2 (3; L = [MeC(N(DIPP))CHC(Me)(NCH 2CH2NMe2)]-, DIPP = 2,6- iPr2C6H3)) are reported. The protonolysis reaction of the yttrium dialkyl [LY(CH2SiMe 3)2] (1) with 1 equiv of 2,6-diisopropylaniline gave the yttrium anilido alkyl [LY(NH(DIPP))(CH2SiMe3)] (2), and a subsequent σ-bond metathesis reaction of 2 with 1 equiv of PhSiH 3 offered the yttrium anilido hydride 3. The structure of 3 was characterized by X-ray crystallography, which showed that the complex is a μ-H dimer. 3 shows high reactivity toward a variety of unsaturated substrates, including imine, azobenzene, carbodiimide, isocyanide, ketone, and Mo(CO)6, giving some structurally intriguing products.