133818-08-3Relevant academic research and scientific papers
Methyl Effects in the Cyclization of γ-Epoxy Bis-Sulfones
Benedetti, Fabio,Berti, Federico,Fabrissin, Silvio,Gianferrara, Teresa,Risaliti, Amerigo
, p. 3530 - 3537 (2007/10/02)
A quantitative study on the effects of methyl and gem-dimethyl groups in the intramolecular ring opening of epoxides by bis-sulfonyl carbanions is reported for the formation of cyclopropanes.Reaction rates are increased by methyl groups on the chain conne
