1338246-46-0

Basic information

• Product Name: C₃₃H₄₄O₄Si
• Synonyms: C₃₃H₄₄O₄Si
• CAS NO: 1338246-46-0
• Molecular Weight: 532.795
• Mol File: 1338246-46-0.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: C₃₃H₄₄O₄Si(CAS DataBase Reference)
• NIST Chemistry Reference: C₃₃H₄₄O₄Si(1338246-46-0)
• EPA Substance Registry System: C₃₃H₄₄O₄Si(1338246-46-0)

Safety Data

• Hazardous Substances Data: 1338246-46-0(Hazardous Substances Data)

Upstream product

• 16838-89-4 2,3,5-tri-O-benzyl-D-xylofuranose 
• 69739-34-0 t-butyldimethylsiyl triflate 
• 201290-06-4 3,4,6-tri-O-benzyl-1,2-dideoxy-D-xylo-hex-1-enitol 

Downstream Products

• 1337989-81-7 tert-butyldimethyl((2R,3R,4S)-1,3,4-tris(benzyloxy)-4-(oxiran-2-yl)butan-2-yloxy)silane 
• 1337989-82-8 5-((tetrahydro-2H-pyran-2-yloxy)methyl)-1-((3S,4R,5R)-3,4,6-tris(benzyloxy)-5-(tert-butyldimethylsilyloxy)-2-hydroxyhexyl)-1H-pyrrole-2-carbaldehyde 
• 1337989-83-9 5-((tetrahydro-2H-pyran-2-yloxy)methyl)-1-((3R,4R,5R)-3,46-tris(benzyloxy)-5-(tert-butyldimethylsilyloxy)-2-oxohexyl)-1H-pyrrole-2-carbaldehyde 
• 1337989-84-0 (2S,3R,4S,5R)-3,4-bis(benzyloxy)-5-(benzyloxymethyl)-1',4,4',5-tetrahydro-3H-spiro[furan-2,3'-pyrrolo[2,1-c][1,4]oxazine]-6'-carbaldehyde 
• 1337990-05-2 (2R,3R,4S,5R)-3,4-bis(benzyloxy)-5-(benzyloxymethyl)-1',4,4',5-tetrahydro-3H-spiro[furan-2,3'-pyrrolo[2,1-c][1,4]oxazine]-6'-carbaldehyde 

Relevant articles and documents

Total synthesis and stereochemical revision of acortatarins A and B

A first total synthesis of acortatarins A, B, and an enantiomer of the proposed structure of acortatarin B is described by using readily available d-sugars. This convergent total synthesis revealed the revision of the absolute configuration of acortatarin A and structural revision of acortatarin B. The key steps involved are regioselective epoxide opening with deprotonated 2,5-disubstituted pyrrole and spiroketalization.