1338258-75-5Relevant academic research and scientific papers
Fluorescent chiral fluorinated liquid crystalline polymers containing rare earth complexes
Yao, Bing,Cong, Yuehua,Zhang, Baoyan
supporting information, p. 3664 - 3670 (2016/05/09)
Fluorescent chiral fluorinated liquid crystalline polymers containing rare earth complexes (RE-LCPs) possessing wonderful liquid crystalline properties and distinct fluorescence properties were graft copolymerized using poly(methylhydrogeno)siloxane (PMHS
Novel photoluminescent chiral liquid crystalline oligomers containing lanthanide ions
Yao, Bing,Cong, Yuehua,Zhang, Baoyan
, p. 87069 - 87076 (2015/11/09)
Novel photoluminescent chiral liquid crystalline oligomers with lanthanide ions (Ln-LCOs) exhibiting excellent liquid crystalline properties and unique fluorescence properties were prepared using poly(methylhydrogeno)siloxane, cholesteric LC M1
Synthesis and characterization of side-chain liquid crystalline polymers and oriented elastomers containing terminal perfluorocarbon chains
Meng, Fan-Bao,Zhang, Xiao-Dong,He, Xiao-Zhi,Lu, He,Ma, Yue,Han, Hui-Li,Zhang, Bao-Yan
, p. 5075 - 5084 (2012/06/18)
Several novel chiral side-chain liquid crystalline (LC) polysiloxane resins containing epoxy groups and mesogenic components have been graft copolymerized by a one-step hydrosilylation reaction with poly(methylhydrogeno)siloxane, an epoxy monomer 2-(allyloxymethyl)oxirane, and chiral fluorinated liquid-crystalline monomers 4′-(4-(allyloxy)benzoyloxy)biphenyl-4-yl 6-(perfluorooctanoyloxy)hexahydrofuro[3,2-b]furan-3-yl adipate and 4′-(4-(undec-10-enoyloxy)benzoyloxy)biphenyl-4-yl 6-(perfluorooctanoyloxy) hexahydrofuro[3,2-b]furan-3-yl adipate. The synthesized epoxy resins are cured using 4,4′-diaminodiphenyl-methane in mesophase state under a magnetic field to obtain crosslinked oriented elastomers. The chemical structures, LC properties and surface morphology of the monomers, the resins and the liquid crystalline elastomers (LCEs) are characterized by use of various experimental techniques such as FTIR, 1H NMR, EA, TGA, DSC, POM, and X-ray measurements. The mesomorphic properties of the synthesized resins and corresponding oriented elastomers are influenced by the terminal perfluorocarbon chains components effectively. The resins show chiral nematic and chiral smectic C phases (Sc*), and Sc* are frozen in their corresponding oriented elastomers. The LC phases are verified by X-ray measurements, and the orientational order parameters of the oriented LCEs are calculated as well.
