1338325-83-9Relevant academic research and scientific papers
Unexpected racemization of 2-hydroxymethylphenylphosphine oxides
Kaczmarczyk, Sylwia,Madalinska, Lidia,Kielbasinski, Piotr
, p. 249 - 253 (2013/07/11)
2-Hydroxymethylphenylphosphine oxides undergo partial racemization in the reaction with mesyl anhydride or mesyl chloride. A possible mechanism is discussed.
Enzymatic synthesis of enantiopure precursors of chiral bidentate and tridentate phosphorus catalysts
Kaczmarczyk, Sylwia,Kwiatkowska, Malgorzata,Madalinska, Lidia,Barbachowska, Agnieszka,Rachwalski, Michal,Blaszczyk, Jaroslaw,Sieron, Leslaw,Kielbasinski, Piotr
, p. 2446 - 2454 (2011/11/04)
The Candida antarctica lipase (CAL-B)-catalyzed acetylation of racemic 2-hydroxymethylphenyl(methyl)phenylphosphine oxide, performed in diethyl ether, led to kinetic resolution with an unusually high enantioselectivity (E=3000). The CAL-B-mediated desymme
