1338672-08-4Relevant academic research and scientific papers
Interaction of carbene and olefin donors with [Cl2PN] 3: Exploration of a reductive pathway toward (PN)3
Al-Rafia, S. M. Ibrahim,Ferguson, Michael J.,Rivard, Eric
scheme or table, p. 10543 - 10545 (2011/12/13)
The iminophosphine-phosphazene [PIII-PV] heterocyclic adduct [IPr?PN(PCl2N)2] was prepared via reduction of the cyclic phosphazene [Cl2PN]3 in the presence of the carbene donor IPr {IPr = [(HCNDipp)2C:], where Dipp = 2,6- iPr2C6H3}. By contrast, the treatment of [Cl2PN]3 with the N-heterocyclic olefin IPr=CH2 yielded the olefin-grafted phosphazene ring [(IPr=CH)P(Cl)N(PCl2N)2].
