1338782-75-4

Upstream product

• 342789-68-8 (E)-methyl 6-O-acetyl-2,3,4-tri-O-benzyl-α-D-manno-hex-5-enopyranoside 
• 34212-64-1 methyl 2,3,4-tri-O-benzyl-α-D-mannopyranoside 
• 40653-15-4 methyl 2,3,4-tri-O-benzyl-α-D-manno-hexodialdo-1,5-pyranoside 

Downstream Products

• 1338782-87-8 C₃₅H₄₂O₁₁ 
• 1338782-86-7 C₆₃H₅₈O₁₅ 
• 1397285-47-0 (1S,3R,5S,6S,7S,8S)-1-O-{(1'S,3'R,5'S,6'S,7'S,8'S)-1'-O-acetyl-6',7',8'-tri-O-benzyl-4'-oxaspiro[2.5]octan-5'-yl}-(5'→1)-6,7,8-tri-O-benzyl-5-O-methyl-4-oxaspiro[2.5]octan 
• 1397285-48-1 (1S,3R,5S,6S,7S,8S)-1-O-{(1'S,3'R,5'R,6'S,7'S,8'S)-1'-O-acetyl-6',7',8'-tri-O-benzyl-4'-oxaspiro[2.5]octan-5'-yl}-(5'→1)-6,7,8-tri-O-benzyl-5-O-methyl-4-oxaspiro[2.5]octan 

Relevant academic research and scientific papers

Reducing the conformational flexibility of carbohydrates: Locking the 6-hydroxyl group by cyclopropanes

The 6-hydroxyl group of hexopyranosides was stereochemically locked by the spiroannelation of a cyclopropane unit at C-5. The corresponding glucose and mannose derivatives were prepared and their behaviour in glycosidation reactions was studied.