1338782-77-6Relevant articles and documents
Reducing the conformational flexibility of carbohydrates: Locking the 6-hydroxyl group by cyclopropanes
Brand, Christian,Granitzka, Markus,Stalke, Dietmar,Werz, Daniel B.
, p. 10782 - 10784 (2011/11/04)
The 6-hydroxyl group of hexopyranosides was stereochemically locked by the spiroannelation of a cyclopropane unit at C-5. The corresponding glucose and mannose derivatives were prepared and their behaviour in glycosidation reactions was studied.