133886-90-5

Upstream product

• 133872-24-9 4-bromobenzenethiol-d₄ 
• 133872-23-8 4-bromobenzenesulfonyl-d₄ chloride 
• 4165-57-5 bromobenzene-d5 

Downstream Products

• 133872-35-2 C₂₆H₁₀⁽²⁾H₈Br₂N₃S₂ 
• 156268-47-2 N-<(4-Bromophenyl-d4)thio>-7-tert-butyl-1-aminopyrene 
• 136490-01-2 N-<(4-bromophenyl-d₄)thio>-2,4,6-triphenyl-d₁₅-aniline 
• 133872-30-7 N¹,N⁵,N⁵-tris<(4-bromophenyl-d₄)thio>-2,4-diphenyl-1,3,5-triazapenta-1,3-diene 
• 136490-36-3 N-<(4-bromophenyl-d₄)thio>-2,4,6-triphenylaniline 

Relevant academic research and scientific papers

Generation, Isolation, and Characterization of N-(Arylthio)-7-tert-butyl- and N-(Arylthio)-2,7-di-tert-butyl-1-pyrenylaminyl Radicals

N-(Arylthio)-7-tert-butyl-1-pyrenylaminyl (2) and N--2,7-di-tert-butyl-1-pyrenylaminyl radicals (3) are prepared by PbO2 oxidation of N-(arylthio)-7-tert-butyl-1-aminopyrenes and N--2,7-di-tert-butyl-1-aminopyrene, respectively, and studied by ESR and ENDOR spectroscopy.The kinetic ESR study shows that, while aminyls 2 gradually decompose in solution at room temperature, aminyl 3 is quite persistent, even in refluxing benzene, and shows no tendency to dimerize, even at low temperatures.These interesting properties of 3 permit us to isolate 3 as radical crystals in 28-31percent yield.The hyperfine splitting (hfs) constants of 2 and 3, determined by ESR and ENDOR spectroscopic methods, show an extensive delocalization of the unpaired electron onto the pyrene ring.Comparison of the hfs constants of 2 and 3 shows that a more extensive delocalization of the spin into the pyrene ring takes place in 3.This is accounted for in terms of the difference in the conformations of 2 and 3.

N1,N5-Bis(arylthio)-2,4-diphenyl-1,3,5-triazapenta-1,3-dienyl Radicals. An Electron Spin Resonance Study

A new class of nitrogen-centered free radicals, N1,N5-bis(arylthio)-2,4-diphenyl-1,3,5-triazapenta-1,3-dienyl radicals 1 have been generated by hydrogen atom abstraction from N1,N5-bis(arylthio)-2,4-diphenyl-1,3