133892-27-0

Downstream Products

• 287376-85-6 cis,cis-[(C6H5)2Pt(μ-S(CH3)2)(μ-(((C6H5)2P)2CH2)Pt(C6H5)2)] 
• 744198-77-4 [Pt(4,4'-diphenyl-6,6'-dimethyl-2,2'-bipyrimidine)(C₆H₅)2]*CH₂Cl₂ 
• 744198-72-9 [Pt(4,4'-diphenyl-6,6'-dimethyl-2,2'-bipyrimidine)(C₆H₅)2] 
• 884508-66-1 K[(pyrrolido[3,2-h]quinoline)PtPh₂] 
• 884508-56-9 K[(2-(2'-pyridyl)indolide)PtPh₂] 
• 1003892-40-7 (Pt(C₆H₅)2(N₂C₇H₅C₅H₃NB(C₆H₂(CH₃)3)2)) 
• 1108202-41-0 PtPh₂(1,3-bis(7-azaindol-1-yl)benzene) 
• 1108202-34-1 PtPh₂(1,2-bis(7-azaindol-1-yl)benzene) 
• 1108202-35-2 PtPh₂(1,3-bis(7-azaindol-1-yl)propane) 
• 1108202-37-4 Pt₂Ph₄(1,3-bis(7-azaindol-1-yl)propane)(SMe₂)2 
• 1108202-36-3 PtPh₂(1,4-bis(7-azaindol-1-yl)butane) 
• 1346416-76-9 Pt(5-B(mesityl)2-5'-NPh₂-2,2'-bipyridine)Ph₂F^(1-) 
• 457057-51-1 PtBr(C₆H₄C₆H₄CHNCH₂C₆H₅)(S(CH₃)2) 

Relevant academic research and scientific papers

Studies of binuclear methyl and phenyl derivatives of platinum(II)

Some reactions of the binuclear organoplatinum complexes , where R = Me or Ph are described, and a new synthetic method for the complex with R = Ph is reported.The dimethylsulphide ligands are easily displaced by other ligands, L, to give cis-.When R = Me, reaction with MeI and Ph2PCH2PPh2, dppm, gives 2(μ-dppm)>, whereas when R = Ph, reaction with MeI gives , which has been characterized as its adduct with 2,2'-bipyridine .The latter complex exists as a mixture of two isomers, though the reaction between and MeI initially gives only one isomer of , formed by trans-oxidative addition.The reaction of with hydrochloric acid yields a 1:1 mixture of and , and it is suggested that this reaction involves an intramolecular methyl group transfer between the platinum atoms of the dimer.