133929-52-9Relevant academic research and scientific papers
Photo-Induced Electron Transfer Reaction of Polysilanes. Intramolecular Trapping of a Transient Silyl Radical Cation with a Nucleophile
Nakadaira, Yasuhiro,Sekiguchi, Akira,Funada, Yasuhito,Sakurai, Hideki
, p. 327 - 330 (2007/10/02)
The radical cation, produced in photo-induced electron transfer of polysilanyl alkanols, can be trapped efficiently intramolecularly with the hydroxyl group.The silyl radical generated in the process is trapped by the solvent employed.A good Hammett relationship is observed in aryldisilanylalkanols between the relative reactivities of the Si-Si bond and ?+ constants of the substituent on the aryl group.
