133961-69-0

Basic information

• Product Name: 6-hydroxy-1,2,3,4-tetrahydrotetraphene-7,12-dione
• Synonyms: 6-hydroxy-1,2,3,4-tetrahydrotetraphene-7,12-dione
• CAS NO: 133961-69-0
• Molecular Weight: 278.307
• Mol File: 133961-69-0.mol

Chemical Properties

• CAS DataBase Reference: 6-hydroxy-1,2,3,4-tetrahydrotetraphene-7,12-dione(CAS DataBase Reference)
• NIST Chemistry Reference: 6-hydroxy-1,2,3,4-tetrahydrotetraphene-7,12-dione(133961-69-0)
• EPA Substance Registry System: 6-hydroxy-1,2,3,4-tetrahydrotetraphene-7,12-dione(133961-69-0)

Safety Data

• Hazardous Substances Data: 133961-69-0(Hazardous Substances Data)

Upstream product

• 194242-28-9 (E,Z)-1-(2'-ethoxy-2'-trimethylsiloxyvinyl)cyclohexene 
• 130-15-4 [1,4]naphthoquinone 

Relevant articles and documents

Studies on Quinones. Part 21. Regioselective Synthesis of Tetracyclic Quinones related to Rabelomycin

The Diels-Alder reaction of the hydroxyquinones 5, 11 and 16 with (E)-1-trimethylsiloxybuta-1,3-diene 3 afforded the corresponding mixture of the regioisomers 6a,b, 12a,b and 17a,b in the ratios 9:1, 8:1 and 11:1, respectively.From these mixtures, the quinones 8, 14 and 19 were obtained by hydrolysis and subsequent oxidation.The preparation of the diene 22 by chlorotrimethylsilylation of the anion of the ester 21 is described.Diels-Alder reaction of diene 22 with the quinones 23 and 24 yielded the corresponding 6-ethoxybenzanthracenequinones 25 and 26, together with the 6-hydroxybenzanthracenequinones 19 and 20.The quinones 10 and 20, which were isolated in mixtures with the ester 21, undergo selective aerial oxidation under basic conditions to give the corresponding benzanthracene-1,7,12-triones 27 and 28.