1339941-27-3Relevant academic research and scientific papers
First examples of spirooxaphosphirane complexes
Perez, Janaina Marinas,Klein, Melina,Kyri, Andreas Wolfgang,Schnakenburg, Gregor,Streubel, Rainer
, p. 5636 - 5640 (2011)
The reaction of a transient Li/Cl phosphinidenoid pentacarbonyltungsten complex (R = CH(SiMe3)2) with cyclohexanone, cyclopentanone, and cyclobutanone yielded the novel, atropisomeric spirooxaphosphirane complexes 3a,b-5a,b, while 2,3-diphenylcyclopropenone furnished selectively the 1,2-dihydrophosphet- 2-one complex 6. All complexes have been characterized by heteronuclear NMR, mass spectrometry, and singlecrystal X-ray analysis in the case of 4a, 5a, and 6.
