13401-21-3Relevant academic research and scientific papers
BENZO[H]QUINOLINE LIGANDS AND COMPLEXES THEREOF
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Page/Page column 76, (2016/12/22)
The present invention provides substituted tridentate benzo[h]quinoline ligands and complexes thereof. The invention also provides the preparation of the ligands and the respective complexes, as well as to processes for using the complexes in catalytic reactions.
Equilibrium acidities of some α,ω-diphenylpolyenes
Thiele, Georg,Streitwieser, Andrew
, p. 446 - 454 (2007/10/02)
Cesium ion pair acidities were measured in THF for a series of diphenylmethane vinylogues that form α,ω-diphenylpolyenyl anions with linearly conjugated chains of 3-9 carbon atoms. The dissociation constants of the diphenylpolyenyls in THF were determined by UV-vis spectroscopy and are rationalized with an electrostatic model. Acidity and dissociation data were combined with measurements of stereoisomer equilibria to estimate the differences in delocalization energy among the diphenylpolyenyl ions. The experimental differences in acidity correlate well with AMI and molecular mechanics (MMPI) calculations.
Fluorescence of α,ω-diphenylpolyenyl carbocations
Young,Brocklehurst,Booth
, p. 7885 - 7888 (2007/10/02)
The fluorescence lifetimes of the α,ω-diphenylpolyenyl carbocations in CH2Cl2 solution increase with decreasing temperature toward limiting values. This behavior is very similar to that of the corresponding α,ω-diphenylpolyenyl carba
