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Upstream product

• 103-83-3 N,N'-dimethylbenzylamine 
• 25855-99-6 1-(4-methylphenyl)-3-phenyl-1,3-propanedione 
• 110-18-9 N,N,N,N,-tetramethylethylenediamine 
• 67-68-5 dimethyl sulfoxide 

Relevant academic research and scientific papers

Acid-promoted oxidative methylenation of 1,3-dicarbonyl compounds with DMSO: Application to the three-component synthesis of Hantzsch-type pyridines

A highly convergent one-pot synthesis of Hantzsch-type pyridines has been developed based on a three-component annulation of 1,3-dicarbonyl compounds, DMSO, and ammonium salt. A transition-metal-free oxidative methylenation reaction/Hantzsch pyridine synt

Oxidative C(Sp3)-H activation and C-N cleavage of N-methyl amines under transition-metal-free condition for synthesis of methylene-bridged bis-1,3-diketones

A transition-metal-free oxidative methylenation reaction was developed. Methylene-bridged bis-1,3-dicarbonyl compounds were synthesized by oxidative C(Sp3)-H activation and C-N cleavage of N-methyl amines. This novel reaction avoids the use of

Aerobic oxidation of a tertiary aliphatic amine under visible-light photocatalysis: Facile synthesis of methylene-bridged bis-1,3-dicarbonyl compounds

Lights, camera, action! An efficient protocol for the formation of methylene-bridged bis-1,3-dicarbonyl compounds has been developed through an aerobic photocatalytic oxidative coupling reaction between 1,3-dicarbonyl compounds and a tertiary aliphatic amine. Copyright

Gold/copper-catalyzed activation of the aci-form of nitromethane in the synthesis of methylene-bridged bis-1,3-dicarbonyl compounds

Activation of the aci-form of nitromethane using Lewis acids for the attack of carbon nucleophiles was studied. 1,3-Dicarbonyl compounds in the presence of catalytic amounts of AuCl3 or Cu(OTf)2 in nitromethane solvent could be converted into methylene-bridged bis-1,3-dicarbonyl compounds.