1340475-96-8Relevant academic research and scientific papers
Oxidative C(Sp3)-H activation and C-N cleavage of N-methyl amines under transition-metal-free condition for synthesis of methylene-bridged bis-1,3-diketones
Wang, Xiaohu,Wang, Yi,Yuan, Yu,Xing, Chun-Hui
, p. 2195 - 2202 (2014/03/21)
A transition-metal-free oxidative methylenation reaction was developed. Methylene-bridged bis-1,3-dicarbonyl compounds were synthesized by oxidative C(Sp3)-H activation and C-N cleavage of N-methyl amines. This novel reaction avoids the use of
Gold/copper-catalyzed activation of the aci-form of nitromethane in the synthesis of methylene-bridged bis-1,3-dicarbonyl compounds
Balamurugan, Rengarajan,Manojveer, Seetharaman
supporting information; experimental part, p. 11143 - 11145 (2011/11/05)
Activation of the aci-form of nitromethane using Lewis acids for the attack of carbon nucleophiles was studied. 1,3-Dicarbonyl compounds in the presence of catalytic amounts of AuCl3 or Cu(OTf)2 in nitromethane solvent could be converted into methylene-bridged bis-1,3-dicarbonyl compounds.
