134078-81-2Relevant articles and documents
Divalent Palladium Catalyzed Stereoselective Synthesis of α-(Z)-(Halomethylene)-γ-butyrolactone Derivatives and Its Mechanism
Ma, Shengming,Lu, Xiyan
, p. 5120 - 5125 (1991)
α-Methylene-γ-butyrolactone rings have been constructed by bis(benzonitrile)palladium dihalide or Pd-(OAc)2-LiX catalyzed cyclization reaction of haloallylic 2-alkynoates.A mechanism involving a trans halopalladation, followed by intramolecular insertion