134079-25-7

Basic information

• Product Name: 1-<2-(Bromomethyl)phenyl>vinyl bromide
• Synonyms: 1-<2-(Bromomethyl)phenyl>vinyl bromide
• CAS NO: 134079-25-7
• Molecular Weight: 275.971
• Mol File: 134079-25-7.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: 1-<2-(Bromomethyl)phenyl>vinyl bromide(CAS DataBase Reference)
• NIST Chemistry Reference: 1-<2-(Bromomethyl)phenyl>vinyl bromide(134079-25-7)
• EPA Substance Registry System: 1-<2-(Bromomethyl)phenyl>vinyl bromide(134079-25-7)

Safety Data

• Hazardous Substances Data: 134079-25-7(Hazardous Substances Data)

Upstream product

• 229027-92-3 {2-[2-(trimethylsilyl)ethynyl]phenyl}methanol 
• 10602-08-1 2-ethynylbenzyl alcohol 
• 211508-95-1 ortho-ethynyl-benzyl bromide 

Downstream Products

• 134079-11-1 6-<2-(1-Bromoethenyl)benzyl>-6-(ethoxycarbonyl)cyclohex-1-en-1-yl triflate 
• 484027-13-6 2-(1-bromo-vinyl)-benzylamine 
• 638213-21-5 2-[2-(1-bromo-vinyl)-benzyl]-isoindole-1,3-dione 
• 134079-05-3 Ethyl 1-<2-(1-bromoethenyl)benzyl>-2-oxocyclohexane-1-carboxylate 

Relevant articles and documents

Free radical-mediated vinyl amination: A mild, general pyrrolidinyl enamine synthesis

The complete scope of free radical-mediated vinyl amination is described, using 5-exo-trig cyclizations of vinyl radicals to the nitrogen of azomethines. The focus is primarily on N,N-dialkyl enamines since their nucleophilicity renders them the most challenging enamines to synthesize using redox conditions. These studies establish several encouraging precedents for the broader application of this strategy.