1341127-72-7Relevant articles and documents
Direct access to β-oxodiazo compounds by copper(II)-catalyzed oxidative rearrangement of stabilized vinyl diazo derivatives
Barluenga, Jose,Lonzi, Giacomo,Riesgo, Lorena,Tomas, Miguel,Lopez, Luis A.
, p. 18138 - 18141 (2011)
The copper(II)-catalyzed reaction of alkenyldiazo compounds with iodosylbenzene leading to β-oxodiazo derivatives is reported. This process occurs via an unprecedented 1,2-shift of the diazoacetate function. A selection of the synthetic applications of a