1341192-62-8

Basic information

• Product Name: C₂₇H₃₅N₃
• Synonyms: C₂₇H₃₅N₃
• CAS NO: 1341192-62-8
• Molecular Weight: 401.595
• Mol File: 1341192-62-8.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: C₂₇H₃₅N₃(CAS DataBase Reference)
• NIST Chemistry Reference: C₂₇H₃₅N₃(1341192-62-8)
• EPA Substance Registry System: C₂₇H₃₅N₃(1341192-62-8)

Safety Data

• Hazardous Substances Data: 1341192-62-8(Hazardous Substances Data)

Upstream product

• 204203-16-7 2,6-bis(1-(2,6-dimethylphenylimino)ethyl)pyridine 

Relevant articles and documents

Synthesis of bis(amino)pyridines by the stepwise alkylation of bis(imino)pyridines: An unexpected and selective alkylation of the aminoiminopyridine by AlMe3

Bis(imino)pyridines 2-[2,6-(R1)2C6H 3N=C(CH3)]-6-[2,6-(R2)2C 6H3N=C(CH3)](C5H3N)(1a, R1 = R2 = i-Pr; 1b, R1 = i-Pr, R2 = CH3; 1c, R1 = R2 = CH3) were first alkylated by AlMe3 and then hydrolyzed to aminoiminopyridines 2-[2,6-(R1)2C6H3N=C(CH 3)]-6-[2,6-(R2)2C6H 3NHC(CH3)2](C5H3N)(3a, R1 = R2 = i-Pr; 3b, R1 = i-Pr, R2 = CH3; 3c, R1 = R2 = CH3). When the aminoiminopyridines were treated with AlMe3, the expected methane elimination was not found; alkylation at the imine functional group led to the aluminum complexes {2-[2,6-(R1)2C6H 3NC(CH3)2]-6-[2,6-(R2) 2C6H3NHC(CH3)2]-(C 5H3N)}AlMe2 (4a, R1 = R2 = i-Pr; 4b, R1 = i-Pr, R2 = CH3; 4c, R 1 = R2 = CH3), which were further hydrolyzed to the bis(amino)pyridines 2-[2,6-(R1)2C6H 3NHC(CH3)2]-6-[2,6-(R2) 2C6H3NHC(CH3)2](C 5H3N)(5a, R1 = R2 = i-Pr; 5b, R 1 = i-Pr, R2 = CH3; 5c, R1 = R 2 = CH3). The selective alkylation over elimination may come from the noninnocent property of the conjugated iminopyridine group. New magnesium, yttrium, and zirconium complexes supported by 5a ({2,6-[2,6-(i-Pr) 2C6H3NC(CH3)2] 2(C5H3N)}Mg(THF)(6), {2,6-[2,6-(i-Pr) 2C6H3NC(CH3)2] 2(C5H3N)}Y(CH2SiMe3)(THF)(7), and {2,6-[2,6-(i-Pr)2C6H3NC(CH3) 2]2(C5H3N)}Zr(CH 2SiMe3)2 (8)) were formed via the alkane elimination method.