1341197-18-9Relevant academic research and scientific papers
Intramolecular direct C-H bond arylation from aryl chlorides: A transition-metal-free approach for facile access of phenanthridines
Wu, Yinuo,Wong, Shun Man,Chan, Tek Long,Kwong, Fuk Yee,Mao, Fei
supporting information, p. 5306 - 5309,4 (2012/12/12)
A C-H arylation with aryl chloride is made viable through a transition-metal-free approach. In the presence of a simple diol associating with KOt-Bu, various phenanthridine derivatives can be conveniently accessed. In particular, only 10 mol % of simple and inexpensive ethylene glycol is required for this protocol. These results represent the first general examples of aryl chloride/C-H coupling under transition-metal-free conditions.
Intramolecular direct C-H bond arylation from aryl chlorides: A transition-metal-free approach for facile access of phenanthridines
Wu, Yinuo,Wong, Shun Man,Mao, Fei,Chan, Tek Long,Kwong, Fuk Yee
supporting information, p. 5306 - 5309 (2013/01/15)
A C-H arylation with aryl chloride is made viable through a transition-metal-free approach. In the presence of a simple diol associating with KOt-Bu, various phenanthridine derivatives can be conveniently accessed. In particular, only 10 mol % of simple and inexpensive ethylene glycol is required for this protocol. These results represent the first general examples of aryl chloride/C-H coupling under transition-metal-free conditions.
