134125-83-0Relevant academic research and scientific papers
Reaction of Thiolo and Selenolo Esters of Phosphorus Acids with Halogens. Part 3. Interaction of O,O,S-Trialkyl Phosphorothioates and O,S-Dialkyl t-Butylphosphonothioates with Sulphuryl Chloride and Halogens
Krawiecka, Bozena,Wojna-Tadeusiak, Elzbieta
, p. 229 - 237 (2007/10/02)
The reaction of the title phosphono- and phosphoro-thiolates with sulphuryl chloride and halogens involves in every case the formation of intermediates containing two phosphorus atoms >P+(SR)OP(O)- (X = SO2Cl or halogen).The formation of the latter in the course of chlorinolysis of phosphorus thiolesters is suggested to be responsible for the occurrence of a mechanism involving retention of configuration.The effect of the structure of the reactants and the nature of solvent on the reaction stereochemistry is discussed.
