134142-29-3

Basic information

• Product Name: endo-3-methyl-5-phenyl-2-oxo-3,4-diazabicyclo<4.1.0>hept-4-ene-7-spiro-1'-indane
• CAS NO: 134142-29-3
• Molecular Weight: 302.376
• Mol File: 134142-29-3.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: endo-3-methyl-5-phenyl-2-oxo-3,4-diazabicyclo<4.1.0>hept-4-ene-7-spiro-1'-indane(CAS DataBase Reference)
• NIST Chemistry Reference: endo-3-methyl-5-phenyl-2-oxo-3,4-diazabicyclo<4.1.0>hept-4-ene-7-spiro-1'-indane(134142-29-3)
• EPA Substance Registry System: endo-3-methyl-5-phenyl-2-oxo-3,4-diazabicyclo<4.1.0>hept-4-ene-7-spiro-1'-indane(134142-29-3)

Safety Data

• Hazardous Substances Data: 134142-29-3(Hazardous Substances Data)

Upstream product

• 2165-04-0 2-methyl-6-phenylpyridazin-3(2H)-one 
• 16275-05-1 1-diazoindane 

Relevant articles and documents

1,3-Dipolar Cycloaddition of 2-Diazoalkanes to Pyridazin-3(2H)-one Derivatives. The Formation of 3H-Pyrazolopyridazin-4(5H)-one and 3H-Pyrazolopyridazin-7(6H)-one Derivatives

1,3-Dipolar cycloadditions of diazoalkanes to pyridazin-3(2H)-ones 1-7 and pyridazin-3(2H)-thiones 8 and 9 are regioselective producing 3H-pyrazolopyridazin-4(5H)-ones 15-19, 27-29 and 34-38 as the major products.In some instances, the isomeric 3H-pyrazolopyridazin-7(6H)-ones, such as 20 and 23 were isolated as the minor products.From 3 and 6 the primary 3a,7a-dihydro cycloadducts 25 and 26, and rearranged 1,2-dihydro intermediate 31 were isolated.From 10 and 1-diazoindane the isomeric exo- and endo-spiro products 39 and 40 were formed.