134149-27-2Relevant academic research and scientific papers
Palladium-mediated cyclopentanation of alkenes bearing a nucleophilic substituent. Stereochemistry and mechanism
Bouyssi, Didier,Balme, Genevieve,Fournet, Guy,Monteiro, Nuno,Gore, Jacques
, p. 1641 - 1644 (1991)
The increased facility of the reaction 11→2. 2 simultaneously with the increased nucleophilicity of the malonate, as well as the stereospecificity observed in the case of 3, led to the conclusion that the cyclisation proceeds by a nucleophilic attack on the double bond activated by a palladium(II) species.
FORMATION DE CYCLOPENTANES A PARTIR DE MALONATES δ-ETHYLENIQUES PAR UN PROCESSUS CATALYTIQUE EN PALLADIUM(0). STEREOCHIMIE ET MECANISME
Balme, Genevieve,Bouyssi, Didier,Faure, Rene,Gore, Jacques,Hemelryck, Bruno van
, p. 3891 - 3902 (2007/10/02)
The treatment of the enolate of a δ-ethylenic malonate with an unsaturated iodide in the presence of a palladium(0) complex leads stereospecifically to a cyclopentane with the simultaneous formation in a trans fashion of the two carbon-carbon bonds.All th
