134151-77-2

Basic information

• Product Name: 1-BroMo-4-(trifluorovinyloxy)benzene
• Synonyms: 4-Bromophenyl trifluorovinyl ether
• CAS NO: 134151-77-2
• Molecular Formula: C₈H₄BrF₃O
• Molecular Weight: 253.0159696
• Mol File: 134151-77-2.mol
• Article Data: 10

Chemical Properties

• Boiling Point: 185.9 °C at 760 mmHg
• Flash Point: 81.7 °C
• Appearance: /
• Density: 1.625 g/cm³
• CAS DataBase Reference: 1-BroMo-4-(trifluorovinyloxy)benzene(CAS DataBase Reference)
• NIST Chemistry Reference: 1-BroMo-4-(trifluorovinyloxy)benzene(134151-77-2)
• EPA Substance Registry System: 1-BroMo-4-(trifluorovinyloxy)benzene(134151-77-2)

Safety Data

• Hazardous Substances Data: 134151-77-2(Hazardous Substances Data)

Usage

General Description

1-Bromo-4-(trifluorovinyloxy)benzene is a chemical compound that belongs to the family of aromatic halides—bromobenzenes in particular—and includes elements such as bromine and trifluorovinyl groups. The presence of a benzene ring in the structure indicates its possible aromatic properties. 1-BroMo-4-(trifluorovinyloxy)benzene, like other bromobenzenes, could potentially be used in organic synthesis where such molecules often serve as building blocks. Additionally, the presence of a trifluorovinyl group suggests that this compound may exhibit some reactivity due to the presence of unsaturated carbon-fluorine bonds. Because detailed chemical and physical properties—stability, reactivity, toxicity—are often specific to individual compounds and not publicly available for all substances like 1-Bromo-4-(trifluorovinyloxy)benzene, caution would be advised when handling and storing this compound.

Upstream product

• 116-14-3 polytetrafluoroethylene 
• 106-41-2 4-bromo-phenol 
• 598-73-2 1-bromo-1,2,2-trifluoroethene 
• 354-26-7 1-chloro-2-iodo-1,1,2-trifluoroethane 
• 68834-05-9 1-bromo-4-(1,1,2,2-tetrafluoroethoxy)benzene 
• 555-16-8 4-nitrobenzaldehdye 
• 113939-45-0 1-bromo-4-(2-bromo-1,1,2,2-tetrafluoroethoxy)benzene 

Downstream Products

• 213701-14-5 (1,2,2-trifluorovinyloxy)phenylboronic acid pinacol ester 
• 852456-77-0 4-[(α,β,β-trifluorovinyl)oxy]benzene dimethyl phosphonate 
• 134377-60-9 1,2-bis(4-bromophenoxyl)hexafluorocyclobutane 
• 1188379-77-2 4-(2-(p-bromophenoxy)perfluorocyclobutoxy)anisole 
• 134151-64-7 1-[1,2,2,3,3,4-hexafluoro-4-(4-methoxyphenoxy)cyclobutoxy]-4-methoxybenzene 
• 1315548-81-2 (Z)-1-(4-bromophenoxy)-2-(2-phenylphenoxy)-1,2-difluoroethene 
• 1315548-82-3 (E)-1-(4-bromophenoxy)-2-(2-phenylphenoxy)-1,2-difluoroethene 
• 1315548-73-2 (Z)-1-(4-bromophenoxy)-1,2-difluoro-2-(4-methoxyphenoxy)ethene 
• 1315548-74-3 (E)-1-(4-bromophenoxy)-1,2-difluoro-2-(4-methoxyphenoxy)ethene 
• 1315548-71-0 (Z)-1-(4-bromophenoxy)-1,2-difluoro-2-phenoxyethene 
• 1315548-72-1 (E)-1-(4-bromophenoxy)-1,2-difluoro-2-phenoxyethene 
• 1315548-84-5 (Z)-1-(4-bromophenoxy)-2-(ethyloxy)-1,2-difluoroethene 
• 1315548-85-6 (E)-1-(4-bromophenoxy)-2-(ethyloxy)-1,2-difluoroethene 
• 1315548-79-8 (Z)-1-(4-bromophenoxy)-2-(2-tert-butylphenoxy)-1,2-difluoroethene 

Relevant articles and documents

METHOD OF MAKING PERFLUOROCYCLOBUTANE-CONTAINING MONOMER

The invention pertains to a multi-step process for making polyfunctional aromatic compounds comprising two phenyl rings bearing reactive groups susceptible of polycondensation reaction to provide polycondensed polymers, said method using economic raw materials, and possessing high selectivity and overall yield.

Method for preparing trifluorovinyl aryl ether compound from dihalide trifluoroethane

The invention relates to a method for synthesizing a trifluorovinyl aryl ether compound, and belongs to the field of chemical synthesis. The dihalide trifluoroethane is taken as the starting material, reacts with a phenolic compound under proper conditions to synthesize the trifluorovinyl aryl ether compound. Compared with the traditional method, the provided synthesis method has the characteristics of mild reaction condition, simple operation, moderate yield and the like, has the advantages of simple process, low cost, low pollution and the like, and is expected to realize industrialized production.

Nucleophilic tetrafluoroethylation employing in situ formed organomagnesium reagents

Tetrafluoroalkyl bromides are metalated with equimolar iPrMgCl·LiCl (Turbo Grignard) to form organomagnesium compounds which are stable at low temperatures and react with various electrophiles (aldehydes, ketones, CO2, cyclic sulfate and sulfamidate, N-sulfonylimines, nitrone, chlorophosphate, nonaflyl azide) to afford novel functionalized tetrafluoroethylene-containing products. Ease of operation, excellent selectivity, high nucleophilicity, and enhanced stability of the reactive species together with a broad substrate scope comprise a highly attractive nucleophilic tetrafluoroethylation protocol affording unique synthetic building blocks.