134176-24-2 Usage
Chemical structure
A tricyclic compound with three cyclohexane rings and an oxygen atom.
Functional groups
Contains a tert-butyldimethylsilyloxy group, which may be used as a protective or reactive group in organic synthesis.
Molecular weight
Approximately 314.56 g/mol (calculated from the molecular formula).
Stereochemistry
The compound may have multiple stereoisomers due to the presence of chiral centers in the cyclohexane rings.
Solubility
Likely soluble in organic solvents such as dichloromethane, ethyl acetate, or acetone, but may have limited solubility in water.
Stability
The compound may be sensitive to hydrolysis or other reactions that could cleave the tert-butyldimethylsilyloxy group.
Potential applications
Due to its intricate structure and potential reactivity, the compound may have applications in pharmaceuticals, agrochemicals, or material science.
Synthesis
The compound can be synthesized through various organic reactions, potentially involving the formation of the tricyclic core and subsequent introduction of the tert-butyldimethylsilyloxy group.
Purification
The compound may require purification techniques such as column chromatography or crystallization to obtain a pure product.
Check Digit Verification of cas no
The CAS Registry Mumber 134176-24-2 includes 9 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 6 digits, 1,3,4,1,7 and 6 respectively; the second part has 2 digits, 2 and 4 respectively.
Calculate Digit Verification of CAS Registry Number 134176-24:
(8*1)+(7*3)+(6*4)+(5*1)+(4*7)+(3*6)+(2*2)+(1*4)=112
112 % 10 = 2
So 134176-24-2 is a valid CAS Registry Number.
InChI:InChI=1/C19H36O3Si/c1-17(2,3)23(7,8)22-12-9-14-13-11-18(4,5)16(20)15(13)19(6,10-12)21-14/h12-16,20H,9-11H2,1-8H3/t12-,13-,14-,15+,16+,19+/m1/s1
134176-24-2Relevant articles and documents
Total Synthesis of Furanether B
Price, Mary E.,Schore, Neil E.
, p. 5662 - 5667 (2007/10/02)
The first total syntheses of furanether B, a member of the lactarane class of sesquiterpenes, have been completed starting from 1-methyl-8-oxabicyclooct-6-en-3-one (3).After ketone reduction, Pauson-Khand cycloaddition (propyne-Co2(CO)6, benzene, heat) gives rise to a 75percent yield of stereoisomeric tricyclic enones 5 and 6.Reduction and methylation of enone 5, removal of the ketone (Barton), and oxidation of the remaining alcohol function give 13.The natural product is obtained upon regiospecific formylation, conversion to the S-butyl derivative, and generation of the furan via a modification of Garst's procedure using a thiomethylene ylide under phase-transfer conditions.A similar sequence beginning with 6 also provides access to 13, but most of the steps proceed in somewhat lower yields.