134180-36-2Relevant academic research and scientific papers
Dienes as Chiral Templates: Easy Access to Pure (2S,3S,4R)-4-Hydroxy-2,3-epoxycyclohex-5-en-1-one
Mauvais, Antony,Winterfeldt, Ekkehard
, p. 5817 - 5822 (2007/10/02)
The title compound 6 was obtained stereospecifically through a concise sequence including a Diels-Alder reaction with the chiral diene 2 and the retro reaction.The Favorskii rearrangement starting from the intermediate epoxide 4 was found to be regioselec
An Easy Access to (S)- and (R)-Hydroxycyclohexenone
Bruenjes, Rainer,Tilstam, Ulf,Winterfeldt, Ekkehard
, p. 1677 - 1678 (2007/10/02)
The Diels-Alder adduct obtained by addition of quinone to the chiral cyclopentadiene 2 undergoes regioselective and stereo-selective reduction after hydrogenation.The 4-hydroxy ketone 3 thus formed yields the title compound 1 in a thermal retro Diels-Alde
