134227-43-3Relevant academic research and scientific papers
Efficient Activation of Acetals, Aldehydes, and Imines toward Silylated Nucleophiles by the Combined Use of Catalytic Amounts of 2 and TMS-CN under Almost Neutral Conditions
Soga, Tsunehiko,Takenoshita, Haruhiro,Yamada, Masaaki,Mukaiyama, Teruaki
, p. 3122 - 3131 (1990)
In the presence of catalytic amount of a transition metal compound such as 2, Co(acac)2, or NiCl2, trimethylsilyl cyanide smoothly reacts with acetals to form α-methoxy carbonitriles in good yields.In the coexistence of catalytic amounts of Rh
Efficient Activation of Acetals toward Nucleophiles with 2 Catalyst. New Method for the Preparation of Aldols from Acetals and Silyl Enol Ethers by the Combined Use of Catalytic Amounts of 2 and Trimethylsilyl Cyanide
Mukaiyama, Teruaki,Soga, Tsunehiko,Takenoshita, Haruhiro
, p. 1273 - 1276 (2007/10/02)
In the presence of a catalytic amount of 2, di-μ-chloro-bis(1,5-cyclooctadiene)dirhodium, trimethylsilyl cyanide smoothly reacts with acetals derived from aliphatic, unsaturated and aromatic aldehydes to form the corresponding α-cyano derivativ
