1342303-49-4Relevant articles and documents
A cationic high-valent Cp*CoIII complex for the catalytic generation of nucleophilic organometallic species: Directed C-H bond activation
Yoshino, Tatsuhiko,Ikemoto, Hideya,Matsunaga, Shigeki,Kanai, Motomu
, p. 2207 - 2211 (2013)
Active without activation: In an inexpensive and atom-economical approach to C-H bond functionalization, a cationic CoIII complex (see scheme) was used to generate nucleophilic organometallic species in situ without additional activating reagen
Rhodium-catalyzed C-H activation and conjugate addition under mild conditions
Yang, Luo,Correia, Camille A.,Li, Chao-Jun
supporting information; experimental part, p. 7176 - 7179 (2011/10/31)
An efficient rhodiumIII-catalyzed C-H activation and subsequent conjugate addition was achieved under mild conditions. The reaction utilized inert arenes to replace stoichiometric organometallic reagents and can tolerate various functional grou