134276-86-1

Upstream product

• 133056-49-2 (+)-(4S,5S)-4-(Methoxymethyl)-5-phenyl-2-(1,4,5-trimethoxy-2-naphthyl)-4,5-dihydroxooxazole 
• 134276-82-7 2-(2-bromo-3,5-dimethoxy-phenyl)-[1,3]dioxolane 

Downstream Products

• 139077-44-4 (+)-(S)-methyl 1-<2-(1,3-dioxolan-2-yl)-4,6-dimethoxyphenyl>-4,5-dimethoxynaphthalene-2-carboxylate 
• 139077-45-5 (+)-(S)-2-<2-(2-hydroxymethyl-4,5-dimethoxy-1-naphthyl)-3,5-dimethoxyphenyl>-1,3-dioxolane 
• 133056-55-0 (-)-(R)-2-(4,5-dimethoxy-2-methyl-1-naphthyl)-3,5-dimethoxybenzaldehyde 

Relevant academic research and scientific papers

Synthetic Approaches to the Alkaloids of the Ancistrocladaceae. Part 3. The Total Synthesis of (-)-Ancistrocladinine: Control of the Diastereoisomer Excess in the Synthesis of Axially Chiral Biaryls.

The total synthesis of the naphthylisoquinoline alkaloid (-)-ancistrocladinine is described.The key step was the construction of the disymmetric bi