134281-85-9

Upstream product

• 1517-82-4 (-)-menthyl p-toluenesulfinate 
• 134281-73-5 (S)-1,1,4,4,5-pentamethoxy-2-p-tolylsulfinyl-1,4-dihydronaphthalene 
• 134281-67-7 (S)-1,4,5-trimethoxy-2-p-tolylsulfinylnaphthalene 

Relevant academic research and scientific papers

Synthesis of Optically Active p-Tolylsulfinylquinones

The title compounds 3a-e were prepared in only two steps from 1,4-dimethoxyaromatic precursors 1a-e by sulfinylation followed by oxidation with ammonium cerium(IV) nitrate.

GENERAL SYNTHESIS OF CHIRAL 2-P-TOLYLSULFINYLQUINONES

Optically pure (S)-p-tolylsulfinyl substituted quinones were synthesized by deketalization of the corresponding quinone bisketals obtained by Andersen's type synthesis starting from 2-bromo-1,4-dimethoxy aromatic derivatives, followed by anodic oxidation