1342819-34-4Relevant academic research and scientific papers
Improved syntheses of phosphine ligands by direct coupling of diarylbromophosphine with organometallic reagents
Liu, Lei,Wu, Hai-Chen,Yu, Jin-Quan
body text, p. 10828 - 10831 (2011/11/04)
Br versus Cl: It is found that the use of diarylbromophosphines instead of diarylchlorophosphines is crucial for their direct coupling with binaphthylmagnesium bromide or BINOL triflate. This finding has led to an improved preparation of both electron-deficient BINAP-type phosphine ligands and several important Buchwald's ligands. Copyright
