134294-57-8Relevant academic research and scientific papers
STEREOCHEMICAL CHARACTERISTICS OF NUCLEOPHILIC SUBSTITUTION IN 2-METHYL-4-CHLOROMETHYL-1,3-DIOXOLANE
Khabibullin, I. R.,Teregulova, G. T.,Rol'nik, L. Z.,Zlotskii, S. S.,Rakhmankulov, D. L.
, p. 932 - 934 (2007/10/02)
Nucleophilic substitution of the chlorine atom in 2-methyl-4-chloromethyl-1,3-dioxolane by mercapto and aryloxy groups was realized.For alkyl hydrosulfides the ratio of the trans and cis isomers in the reaction products was 6:4.The trans isomer also predominates in the reaction products if the chlorine is substituted by an aryloxy group.
