134297-05-5

Basic information

• Product Name: 2-Buten-1-ol, 4-[[(1,1-dimethylethyl)dimethylsilyl]oxy]-
• Synonyms: .(2Z)-4-{[tert-butyl(dimethyl)silyl]oxy}but-2-en-1-ol;.(Z)-4-(tert-butyl-dimethylsilanyloxy)but-2-en-1-ol;.cis-4-(tert-butyl-dimethyl-silanyloxy)-but-2-en-1-ol;.(Z)-4-(tert-butyl-dimethyl-silanyloxy)-but-2-en-1-ol;.(2Z)-4-(tert-butyldimethylsilanyloxy)but-2-en-1-ol;(Z)-4-hydroxy-1-(tert-butyldimethylsilyloxy)but-2-ene
• CAS NO: 134297-05-5
• Molecular Formula: C10H22O2Si
• Molecular Weight: 202.369
• Mol File: 134297-05-5.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: 2-Buten-1-ol, 4-[[(1,1-dimethylethyl)dimethylsilyl]oxy]-(CAS DataBase Reference)
• NIST Chemistry Reference: 2-Buten-1-ol, 4-[[(1,1-dimethylethyl)dimethylsilyl]oxy]-(134297-05-5)
• EPA Substance Registry System: 2-Buten-1-ol, 4-[[(1,1-dimethylethyl)dimethylsilyl]oxy]-(134297-05-5)

Safety Data

• Hazardous Substances Data: 134297-05-5(Hazardous Substances Data)

Downstream Products

• 869586-05-0 N-(5-bromo-2-iodo-4-methoxyphenyl)-N-[4-(tert-butyldimethylsilanyloxy)but-2-enyl]-2,2,2-trifluoroacetamide 
• 869740-11-4 (Z)-N-(2-[4-(tert-butyl-dimethyl-silanyloxy)-but-2-enyloxy]-1,3-dimethyl-2λ⁵-[1,3,2]diazaphospholidin-2-ylidene)-4-methyl-benzenesulfonamide 
• 646059-50-9 4-tert-butyldiphenylsiloxy-2Z-buten-1-yl 4,6-O-benzylidene-2,3-di-O-p-bromobenzyl-β-D-mannopyranoside 
• 646059-67-8 4-tert-butyldiphenylsiloxy-2Z-buten-1-yl 4,6-O-benzylidene-2,3-di-O-p-bromobenzyl-α-D-mannopyranoside 
• 1053699-90-3 [(1R,2S)-2-(tert-Butyl-dimethyl-silanyloxy)-4-[1,3]dioxolan-2-yl-1-phenethyl-butyl]-((S)-2-methoxymethyl-pyrrolidin-1-yl)-carbamic acid methyl ester 
• 1026076-65-2 {(R)-1-[(S)-1-(tert-Butyl-dimethyl-silanyloxy)-3-phenyl-propyl]-pentyl}-((S)-2-methoxymethyl-pyrrolidin-1-yl)-carbamic acid methyl ester 
• 421579-73-9 [(R)-3-Benzyloxy-2-(tert-butyl-dimethyl-silanyloxy)-prop-(E)-ylidene]-((S)-2-methoxymethyl-pyrrolidin-1-yl)-amine 

Relevant articles and documents

Deprotection of a silyl group with mesoporous silica

The triethylsilyl (TES) group of silyl ethers of several types is selectively and easily removed in the presence of a t-butyldimethylsilyl (TBDMS) group with a mesoporous silica MCM-41/MeOH heterogeneous system. Comparison of the efficiency was carried out among several solvents, and among such promoters as common zeolites and ion-exchange resins. Furthermore, FSM-16, another mesoporous silica, was examined for the possibility of recycling by re-calcination at 400°C after the reaction.