1343504-98-2

Basic information

• Product Name: RuCl(CO)(P(C₆H₅)3)(C₅H₄NCONHNCHC₆H₃OCl)
• CAS NO: 1343504-98-2
• Molecular Weight: 701.511
• Mol File: 1343504-98-2.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: RuCl(CO)(P(C₆H₅)3)(C₅H₄NCONHNCHC₆H₃OCl)(CAS DataBase Reference)
• NIST Chemistry Reference: RuCl(CO)(P(C₆H₅)3)(C₅H₄NCONHNCHC₆H₃OCl)(1343504-98-2)
• EPA Substance Registry System: RuCl(CO)(P(C₆H₅)3)(C₅H₄NCONHNCHC₆H₃OCl)(1343504-98-2)

Safety Data

• Hazardous Substances Data: 1343504-98-2(Hazardous Substances Data)

Upstream product

• 157072-60-1 (carbonyl)(chloro)(hydrido)tris(triphenylphosphine)ruthenium(II) 
• 732-92-3 5-chlorosalicylaldehyde isonicotinoyl hydrazone 

Relevant articles and documents

Ruthenium(II) hydrazone Schiff base complexes: Synthesis, spectral study and catalytic applications

Ruthenium(II) hydrazone Schiff base complexes of the type [RuCl(CO)(B)(L)] (were B = PPh3, AsPh3 or Py; L = hydrazone Schiff base ligands) were synthesized from the reactions of hydrazone Schiff base ligand (obtained from isonicotinoylhydrazide and different hydroxy aldehydes) with [RuHCl(CO)(EPh3)2(B)] (where E = P or As; B = PPh 3, AsPh3 or Py) in 1:1 molar ratio. All the new complexes have been characterized by analytical and spectral (FT-IR, electronic, 1H, 13C and 31P NMR) data. They have been tentatively assigned an octahedral structure. The synthesized complexes have exhibited catalytic activity for oxidation of benzyl alcohol to benzaldehyde and cyclohexanol to cyclohexanone in the presence of N-methyl morpholine N-oxide (NMO) as co-oxidant. They were also found to catalyze the transfer hydrogenation of aliphatic and aromatic ketones to alcohols in KOH/Isopropanol.