1343516-19-7Relevant academic research and scientific papers
Organocatalytic asymmetric synthesis of N,N-bis(dihydrofuranyl) hydroxyamines: A cascade reaction involving friedelcrafts alkylation, internal redox reaction umpolung
Sohtome, Yoshihiro,Yamaguchi, Takahisa,Shin, Bongki,Nagasawa, Kazuo
, p. 843 - 845 (2011)
Stereoselective syntheses of N,N-bis(dihydrofuranyl)- hydroxyamines from phenols and nitroolefins have been accomplished by means of cycle-specific catalysis with guanidine/bisthiourea organocatalyst and achiral base. Circumstantial evidence supports the idea that a nitroso intermediate participates in the dimerization, which involves internal redox reaction/umpolung.
