1343516-72-2Relevant academic research and scientific papers
Ru3(CO)12-catalyzed dehydrogenative Si–N coupling of indoles with hydrosilanes without additive
Zhai, Wenchao,Li, Bin,Wang, Baiquan
, p. 1123 - 1128 (2018/02/12)
An efficient Ru3(CO)12-catalyzed dehydrogenative Si–N coupling reaction of indoles, pyrrole, and carbazole with hydrosilanes is reported. The reaction does not need any external additive. This catalytic reaction has a wide substrate range, excellent functional group tolerance, and high to excellent reaction efficiency. Gram-scale synthesis demonstrates the practicability of this synthetic method.
Zinc-catalyzed dehydrogenative N-silylation of indoles with hydrosilanes
Tsuchimoto, Teruhisa,Iketani, Yoshihiko,Sekine, Masaru
supporting information; experimental part, p. 9500 - 9504 (2012/09/21)
Zinc catalysis: Zinc triflate in a nitrile solvent behaved as an effective catalyst for dehydrogenative N-silylation with a variety of indoles and hydrosilanes (see scheme). The addition of pyridine greatly accelerated the N-silylation reaction to produce N-silylindoles exclusively in high to excellent yields. Copyright
