134355-02-5Relevant articles and documents
Direct synthesis of 2-deoxy-β-glycosides via anomeric O-alkylation with secondary electrophiles
Zhu, Danyang,Baryal, Kedar N.,Adhikari, Surya,Zhu, Jianglong
supporting information, p. 3172 - 3175 (2014/03/21)
An approach for direct synthesis of biologically significant 2-deoxy-β-glycosides has been developed via O-alkylation of a variety of 2-deoxy-sugar-derived anomeric alkoxides using challenging secondary triflates as electrophiles. It was found a free hydroxyl group at C3 of the 2-deoxy-sugar-derived lactols is required in order to achieve synthetically efficient yields. This method has also been applied to the convergent synthesis of a 2-deoxy-β-tetrasaccharide.
Synthesis of the core trisaccharide of esperamicin: corroboration of the proposed structure for its rearrangement product and stabilization of the core trisaccharide domain
Halcomb, Randall L.,Wittman, Mark D.,Olson, Steven H.,Danishefsky, Samuel J.,Golik, Jerzy,Wong, Henry,Vyas, Dolatrai
, p. 5080 - 5082 (2007/10/02)
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