134360-99-9

Basic information

• Product Name: Lithium; (Z)-1-pyrrolidin-1-yl-propen-1-olate
• CAS NO: 134360-99-9
• Molecular Weight: 133.119
• Mol File: 134360-99-9.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: Lithium; (Z)-1-pyrrolidin-1-yl-propen-1-olate(CAS DataBase Reference)
• NIST Chemistry Reference: Lithium; (Z)-1-pyrrolidin-1-yl-propen-1-olate(134360-99-9)
• EPA Substance Registry System: Lithium; (Z)-1-pyrrolidin-1-yl-propen-1-olate(134360-99-9)

Safety Data

• Hazardous Substances Data: 134360-99-9(Hazardous Substances Data)

Upstream product

• 4553-05-3 1-pyrrolidin-1-yl-propan-1-one 

Relevant articles and documents

On the Structure and Reactivity of Lithium Diisopropylamide (LDA) in Hydrcarbon Solutions. Formation of Unsolvated Ketone, Ester, and Carboxamide Enolates

Enolizations of ketones, tert-butyl esters, and carboxamides by solvent-free lithium diisopropylamide (LDA) in hexane or toluene are described.Enolates are isolated as spectroscopically pure, white (often crystalline) solids.Solubilities of the enolates in hexane range from highly soluble to completely insoluble.Enolization of aldehydes, methyl esters, and acetone afford complex mixtures.Analysis of LDA and LDA in hexane by 6Li and 15N NMR spectroscopy show evidence of an equilibrium mixture of at least three cyclic oligomers.