134377-56-3Relevant academic research and scientific papers
Synthesis and electronic factors in thermal cyclodimerization of functionalized aromatic trifluorovinyl ethers
Spraul, Bryan K.,Suresh,Jin, Jianyong,Smith Jr., Dennis W.
, p. 7055 - 7064 (2007/10/03)
A series of 19 p-substituted aromatic trifluorovinyl ether compounds were prepared from versatile intermediate P-Br-C6H4-O-CF= CF2 and underwent thermal radical mediated cyclodimerization to new difunctional compounds cont
Reactive compounds containing perfluorocyclobutane rings
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, (2008/06/13)
Novel compounds have at least one perfluorocyclobutane ring and at least two functional groups suitable for forming condensation polymers. Preferably the compounds have a structures represented by Formula II: STR1 wherein R and R' independently represent optionally inertly substituted groups; X and X' represent any molecular structures which link R and R' with the perfluorocyclobutane ring; n and n' are the number of G and G' groups, respectively; and G and G' independently represent any reactive functional groups or any groups convertible into reactive functional groups. The compound are preferably prepared by a process of thermally dimerizing trifluorovinyl compound to form a compounds of Formula I wherein G represents G or G' in Formula II; X represents X or X' of Formual II; and n represents n or n' of Formula II, to form a compound having a perfluorocyclobutane group.
