1344030-14-3Relevant academic research and scientific papers
The first selective one-pot synthesis of 1,3-dicarbonyl adamantanes from adamantane and 1,3-dimethyladamantane
Akhrem, Irena S.,Avetisyan, Dzhul'Etta V.,Afanas'Eva, Luidmila V.
, p. 3493 - 3496 (2012)
A new approach to a simple one-pot functionalization of adamantane and 1,3-dimethyladamantane with CO and various nucleophiles in the presence of the superelectrophilic complex, CBr4·2AlBr3 provides access to important 1,3-dicarbonyl adamantanes with two new functional groups at the bridge-head positions.
The first one-pot synthesis of 1,3-dicarbonyl adamantanes from 1-bromoadamantanes
Akhrem, Irena S.,Avetisyan, Dzhul'Etta V.,Afanas'Eva, Lyudmila V.,Goryunov, Evgenii I.,Churilova, Irina M.,Petrovskii, Pavel V.,Kagramanov, Nikolai D.
, p. 259 - 261 (2011)
Treatment of 1-bromoadamantane and 1-bromo-3,5-dimethyladamantane with CBr4·2AlBr3 under carbon monoxide atmosphere followed by quenching with nucleophiles affords 1,3-dicarbonyl adamantanes.
