134419-78-6Relevant articles and documents
ICl-induced intramolecular electrophilic cyclization of 1-[4′-methoxy(1,1′-biphenyl)2-yl]alkynones - A facile approach to spiroconjugated molecules
Chen, Yu,Liu, Xiaochen,Lee, Minwook,Huang, Chenlong,Inoyatov, Igor,Chen, Zhiwei,Perl, Abraham C.,Hersh, William H.
, p. 9795 - 9799 (2013)
Spiro compounds: An iodine monochloride-induced intramolecular cyclization of 1-[4′-methoxy(1,1′-biphenyl)2-yl]alkynones has been developed (see scheme). An electrophilic iodocyclization selectively takes place at the ipso position (versus the ortho elect
Gold-Catalyzed Oxidation/C?H Functionalization of Ynones: Efficient and Rapid Access to Functionalized Polycyclic Salicyl Ketones
Ji, Kegong,Yang, Fang,Gao, Shiyue,Tang, Jiangjiang,Gao, Jinming
supporting information, p. 10225 - 10229 (2016/07/19)
An efficient strategy to construct salicyl ketones through gold-catalyzed oxidation/C?H functionalization of ynones is reported. A variety of functionalized salicyl ketones are readily accessed by utilizing this non-diazo approach, thus providing a viable
Synthesis of dibenzocyclohepten-5-ones by electrophilic iodocyclization of 1-([1,1′-Biphenyl]-2-yl)alkynones
Chen, Yu,Huang, Chenlong,Liu, Xiaochen,Perl, Eliyahu,Chen, Zhiwei,Namgung, Jieun,Subramaniam, Gopal,Zhang, Gan,Hersh, William H.
, p. 3452 - 3464 (2014/05/06)
A synthesis of iodo-substituted dibenzocyclohepten-5-ones by the iodine monochloride (or iodine)-induced intramolecular 7-endo-dig cyclization of 1-([1,1′-biphenyl]-2-yl)alkynones is reported. Detailed investigations on the substituent effects during the
