134427-71-7Relevant academic research and scientific papers
Rh(II)-Catalyzed asymmetric carbene transfer with ethyl 3,3,3-trifluoro-2-diazopropionate
Müller, Paul,Grass, Stéphane,Shahi, Shatrughan P.,Bernardinelli, Gérald
, p. 4755 - 4763 (2004)
The asymmetric cyclopropanation of 1,1-diphenylethylene (2) with ethyl 3,3,3-trifluoro-2-diazopropionate (1) in the presence of chiral Rh(II) catalysts affords cyclopropane 3 with yields and enantioselectivities of up to 72 and 40%, respectively. Similar
Carbenoid entry into trifluoromethylated molecules: Preparation of functionalized CF3-containing γ, δ-unsaturated carboxylic esters by rhodium-catalyzed reaction of ethyl 3,3,3-trifluoro-2-diazo-propionate with allylic sulfides and their furthe
Shi, Guoqiang,Xu, Yuanyao,Xu, Ming
, p. 1629 - 1648 (2007/10/02)
The [2,3]-sigmatropic rearrangement of sulfonium ylides derived from rhodium-catalyzed decomposition of ethyl 3,3,3-trifluoro-2-diazopropionate in the presence of allylic sulfides affords a variety of functionalized CF3-containing γ, δ-unsatura
