1345017-49-3

Upstream product

• 1345017-47-1 (S)-tert-butyl 4-((R)-1-(allyloxy)allyl)-2,2-dimethyloxazolidine-3-carboxylate 
• 1345017-48-2 tert-butyl (2S,3R)-3-(allyloxy)-1-hydroxypent-4-en-2-ylcarbamate 
• 58479-61-1 tert-butylchlorodiphenylsilane 
• 102308-32-7 (4S)-4-formyl-2,2-dimethyl-oxazolidine-3-carboxylic acid tert-butyl ester 
• 114301-34-7 tert-butyl (S)-4-((R)-1-hydroxyallyl)-2,2-dimethyloxazolidine-3-carboxylate 

Downstream Products

• 1345017-50-6 tert-butyl (2R,6R,E)-1-(tert-butyldiphenylsilyloxy)-6-hydroxyocta-3,7-dien-2-ylcarbamate 
• 1345017-51-7 tert-butyl (2R,6S,E)-1-(tert-butyldiphenylsilyloxy)-6-hydroxyoct-3-en-2-ylcarbamate 
• 1345017-52-8 (3S,7R,E)-7-(tert-butoxycarbonylamino)-8-(tert-butyldiphenylsilyloxy)oct-5-en-3-yl acetate 
• 1345017-53-9 (3S,5S,6S,7S)-7-((tert-butoxycarbonyl)amino)-8-((tert-butyldiphenylsilyl)oxy)-5,6-dihydroxyoctan-3-yl acetate 
• 1345017-54-0 (3S,5R,6R,7S)-7-((tert-butoxycarbonyl)amino)-8-((tert-butyldiphenylsilyl)oxy)-5,6-dihydroxyoctan-3-yl acetate 
• 1345017-55-1 (S)-1-((4S,5S)-2,2-dimethyl-5-((S)-2,2,10,10-tetramethyl-8-oxo-3,3-diphenyl-4,9-dioxa-7-aza-3-silaundecan-6-yl)-1,3-dioxolan-4-yl)butan-2-yl acetate 
• 1345017-56-2 tert-butyl ((S)-2-((tert-butyldiphenylsilyl)oxy)-1-((4S,5S)-5-((S)-2-hydroxybutyl)-2,2-dimethyl-1,3-dioxolan-4-yl)ethyl)carbamate 
• 1345017-57-3 (3aS,4S,6R,7aS)-tert-butyl-4-((tert-butyldiphenylsilyloxy)methyl)-6-ethyl-2,2-dimethyltetrahydro-[1,3]dioxolo[4,5-c]pyridine-5(6H)-carboxylate 
• 1345017-59-5 (S)-1-((4R,5R)-2,2-dimethyl-5-((S)-2,2,10,10-tetramethyl-8-oxo-3,3-diphenyl-4,9-dioxa-7-aza-3-silaundecan-6-yl)-1,3-dioxolan-4-yl)butan-2-yl acetate 
• 1345017-60-8 tert-butyl ((S)-2-((tert-butyldiphenylsilyl)oxy)-1-((4R,5R)-5-((S)-2-hydroxybutyl)-2,2-dimethyl-1,3-dioxolan-4-yl)ethyl)carbamate 
• 1345017-61-9 (3aR,4S,6R,7aR)-tert-butyl-4-((tert-butyldiphenylsilyloxy)methyl)-6-ethyl-2,2-dimethyltetrahydro-[1,3]dioxolo[4,5-c]pyridine-5(6H)-carboxylate 
• 1345017-63-1 (3R,7R,E)-7-(tert-butoxycarbonylamino)-8-(tert-butyldiphenylsilyloxy)octa-1,5-dien-3-yl acrylate 

Relevant academic research and scientific papers

[2,3]-Wittig rearrangement approach to iminosugar C-glycosides: 5-epi-ethylfagomine, 2-epi-5-deoxyadenophorine and formal synthesis of indolizidine 167B and 209D

A new strategy for the synthesis of 1,2-dideoxy iminosugar C-glycosides and indolizidines involving highly stereoselective [2,3]-Wittig rearrangement from Garner aldehyde has been developed. This rearrangement yielded an optically pure, highly functionali