1345024-11-4Relevant articles and documents
Total syntheses of (+)-pestaphthalide A and (-)-pestaphthalide B
Schwaben, Jonas,Cordes, Jens,Harms, Klaus,Koert, Ulrich
, p. 2929 - 2934 (2011/10/30)
Total syntheses of (+)-pestaphthalide A and (-)-pestaphthalide B were achieved. Key steps are an iridium-mediated meta-selective arylborylation, a Suzuki-coupling/Jacobsen-epoxidation sequence, a stereodivergent epoxide opening and an anionic cyclic carbonate/-lactone rearrangement. Georg Thieme Verlag Stuttgart - New York.