1345093-37-9

Basic information

• Product Name: PdBrC₆H₄(CH₂)3CH₃C₆H₂(CH(CH₃)2)3C₆H₂(OCH₃)2P(C(CH₃)3)2
• CAS NO: 1345093-37-9
• Molecular Weight: 804.24
• Mol File: 1345093-37-9.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: PdBrC₆H₄(CH₂)3CH₃C₆H₂(CH(CH₃)2)3C₆H₂(OCH₃)2P(C(CH₃)3)2(CAS DataBase Reference)
• NIST Chemistry Reference: PdBrC₆H₄(CH₂)3CH₃C₆H₂(CH(CH₃)2)3C₆H₂(OCH₃)2P(C(CH₃)3)2(1345093-37-9)
• EPA Substance Registry System: PdBrC₆H₄(CH₂)3CH₃C₆H₂(CH(CH₃)2)3C₆H₂(OCH₃)2P(C(CH₃)3)2(1345093-37-9)

Safety Data

• Hazardous Substances Data: 1345093-37-9(Hazardous Substances Data)

Upstream product

• 225931-80-6 bis[(trimethylsilyl)methyl](1,5-cyclooctadiene)palladium(II) 
• 1160861-53-9 t-BuBrettPhos 
• 41492-05-1 p-bromobutylbenzene 

Relevant articles and documents

Evidence for in situ catalyst modification during the Pd-catalyzed conversion of aryl triflates to aryl fluorides

A mechanistic investigation of the Pd-catalyzed conversion of aryl triflates to fluorides is presented. Studies reveal that C-F reductive elimination from a LPdII(aryl)F complex (L = t-BuBrettPhos or RockPhos) does not occur when the aryl group is electron rich. Evidence is presented that a modified phosphine, generated in situ, serves as the actual supporting ligand during catalysis with such substrates. A preliminary study of the reactivity of a LPdII(aryl)F complex based on this modified ligand is reported.