13453-78-6

Basic information

• Product Name: Lithium perchlorate trihydrate
• Synonyms: LITHIUM PERCHLORATE HYDRATE;LITHIUM PERCHLORATE TRIHYDRATE;Lithium perchlorate trihydrate, extra pure, 99+%;LITHIUM PERCHLORATE, TRIHYDRATE (ACS) REAGENT;Lithiumperchloratetrihydrate,98%;Perchloric acid, lithium salt, trihydrate;lithium perchlorate trihydrate, reagent grade;Lithium pechlorate trihydrate
• CAS NO: 13453-78-6
• Molecular Formula: ClH6LiO7
• Molecular Weight: 160.44
• EINECS: 232-237-2
• Product Categories: Oxidation;Perchlorates;Synthetic Reagents;metal perchlorate salt
• Mol File: 13453-78-6.mol
• Article Data: 0

Chemical Properties

• Melting Point: 95 °C
• Boiling Point: decomposes at 470℃ [KIR79]
• Appearance: White/Crystals and/or Chunks
• Density: 1.841 g/mL at 25 °C(lit.)
• Water Solubility: 597 g/L (25 ºC)
• Sensitive: Hygroscopic
• Stability: hygroscopic
• Merck: 14,5539
• CAS DataBase Reference: Lithium perchlorate trihydrate(CAS DataBase Reference)
• NIST Chemistry Reference: Lithium perchlorate trihydrate(13453-78-6)
• EPA Substance Registry System: Lithium perchlorate trihydrate(13453-78-6)

Safety Data

• Hazard Codes: O,Xi
• Statements: 8-36/37/38
• Safety Statements: 17-26-27-36/37/39-37/39
• RIDADR: UN 1481 5.1/PG 2
• WGK Germany: 1
• RTECS: SC8750000
• TSCA: Yes
• HazardClass: 5.1
• PackingGroup: II
• Hazardous Substances Data: 13453-78-6(Hazardous Substances Data)

Usage

Description

Lithium perchlorate trihydrate (LiClO4.3H2O) is a white crystalline compound with pyroelectric properties. It is a versatile chemical with various applications across different industries due to its unique properties.

Uses

Used in Chemical Synthesis:
Lithium perchlorate trihydrate is used as an oxidizing agent for various chemical reactions, providing a controlled and efficient source of oxygen.
Used in Chemical Oxygen Generators:
Lithium perchlorate trihydrate is used as an oxygen source in chemical oxygen generators, as it liberates oxygen at high temperatures, making it suitable for emergency oxygen supply systems.
Used in Diels-Alder Reactions:
Lithium perchlorate trihydrate is used as a catalyst in Diels-Alder reactions, taking advantage of its excellent solubility to facilitate the coupling of alpha, beta-unsaturated carbonyl compounds with aldehydes.
Used in Lithium-ion Batteries:
Lithium perchlorate trihydrate is used as an electrolyte in lithium-ion batteries, enhancing their performance and efficiency.
Used as a Chaotropic Agent:
Lithium perchlorate trihydrate is used as a chaotropic agent to denature proteins, which is essential in various biochemical and biophysical applications.
Used in the Baylis-Hillman Reaction:
Lithium perchlorate trihydrate is used as a catalyst in the Baylis-Hillman reaction, promoting the coupling of alpha, beta-unsaturated carbonyl compounds with aldehydes to form valuable synthetic intermediates.

InChI:InChI=1/ClHO4.Li.3H2O/c2-1(3,4)5;;;;/h(H,2,3,4,5);;3*1H2/q;+1;;;/p-1