13453-86-6

Basic information

• Product Name: LITHIUM BISULFATE
• Synonyms: LITHIUM BISULFATE;lithium hydrogen sulphate;Lithium hydrogensulfate;Sulfuric acid hydrogen lithium salt
• CAS NO: 13453-86-6
• Molecular Formula: HO₄S*Li
• Molecular Weight: 104.01
• EINECS: 236-635-7
• Mol File: 13453-86-6.mol

Chemical Properties

• Boiling Point: 330°Cat760mmHg
• Flash Point: °C
• Appearance: /
• Density: g/cm³
• CAS DataBase Reference: LITHIUM BISULFATE(CAS DataBase Reference)
• NIST Chemistry Reference: LITHIUM BISULFATE(13453-86-6)
• EPA Substance Registry System: LITHIUM BISULFATE(13453-86-6)

Safety Data

• Hazardous Substances Data: 13453-86-6(Hazardous Substances Data)

Usage

Uses

Used in Electrolyte Solutions for Lithium Batteries:
Lithium bisulfate is used as a component in electrolyte solutions for lithium batteries. It facilitates the movement of lithium ions between the battery's electrodes, enhancing the battery's performance and efficiency.
Used in Organic Synthesis:
Lithium bisulfate is used as a reagent in organic synthesis, where it aids in various chemical reactions. Its unique properties make it a valuable component in the synthesis of organic compounds.
Used in Chemical Reactions:
Lithium bisulfate is utilized as a reagent in chemical reactions, contributing to the formation of desired products. Its presence can influence the reaction pathways and improve the yield of the target compounds.

InChI:InChI=1/Li.H2O4S/c;1-5(2,3)4/h;(H2,1,2,3,4)/q+1;/p-2

Upstream product

• 7664-93-9 sulfuric acid 
• 554-13-2 lithium carbonate 

Relevant articles and documents

Synthesis and Crystal Structure of LiHSO4

Single crystals of the new compound LiHSO4 are synthesized from the system Lithiumsulfate/Sulfuric acid. The up to day not determined structure of the title compound is monoclinic, space group P21/C with the lattice constants a=5.234(2), b=7.322(1) and c=

X-ray diffraction study of lithium hydrazinium sulfate and lithium ammonium sulfate crystals under a static electric field

X-ray diffraction studies are made on proton-conducting polar lithium hydrazinium sulfate and ferroelectric lithium ammonium sulfate. The X-ray rocking curves recorded with in situ electric field along the polar b axis of lithium hydrazinium sulfate (direction of proton conductivity) show a strong enhancement of the 0k0 diffraction intensity. The corresponding 0k0 X-ray topographs reveal extinction contrast consisting of striations parallel to the polar axis. They disappear when the electric field is switched off. The effect is very strong in 0k0 but invisible in h0l reflections. It is present only if the electric field is parallel to the polar axis b. This unusual X-ray topographic contrast is correlated with the proton conduction. It is supposed that, under electric field, an inhomogeneous charge distribution develops, distorting the crystal lattice. Similar experiments on lithium ammonium sulfate also show contrast variations, but of quite different behaviour than before. In this case they result from changes of the ferroelectric domain configuration under electric field.